Lecture 17: Liquid-Liquid Spinodal Decomposition; Introduction to Systems with Chemical Reactions
MIT 2.43 Advanced Thermodynamics, Spring 2024
Instructor: Gian Paolo Beretta
View the complete course: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/
Complete course table of contents with hyperlinks to slides and video timestamps: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_toc_slides_pdf/
Complete course analytical index with hyperlinks to slides and video timestamps: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_index_slides_pdf/
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP6309d0oJDiVo1CvxUQXJ2il
This lecture covers: Henry law. Lennard-Jones binary mixture model. Stability and miscibility gap. Liquid-liquid spinodal decomposition. Energy and entropy balances for open and closed systems with chemical reactions. Bond strength versus van der Waals force.
Instructor suggests to set viewing speed at 1.5 for faster learning.
Slides for this lecture: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_lec17_pdf/
Key moments:
00:00:00 - Introduction
00:00:23 - Liquid-Vapor Equilibria for Non-Ideal Mixtures
00:05:01 - Henry's Law for Dilute Non-Ideal Solutions
00:16:53 - Careful in Taking Derivatives!
00:27:25 - Stability Conditions for a Binary Mixtures
00:34:52 - Non-Ideal Mixture Behavior: Complete Miscibility
00:36:45 - Non-Ideal Mixture Behavior: Partial Miscibility
00:38:21 - Spinodal Decomposition
00:42:11 - The “Ouzo Effect”
00:54:06 - Introduction to Systems with Chemical Reactions
00:54:27 - Energy and Entropy Balances with Chemical Reaction
01:07:06 - Notation and Stoichiometry: Reaction Coordinates
01:19:23 - Proportionality Relations; Properties of Reaction
01:28:42 - Enthalpy of Formation Illustrated on a H-S Diagram
01:34:52 - Van der Waals Forces versus Covalent Bonds
License: Creative Commons BY-NC-SA
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Chapters (15)
Introduction
0:23
Liquid-Vapor Equilibria for Non-Ideal Mixtures
5:01
Henry's Law for Dilute Non-Ideal Solutions
16:53
Careful in Taking Derivatives!
27:25
Stability Conditions for a Binary Mixtures
34:52
Non-Ideal Mixture Behavior: Complete Miscibility
36:45
Non-Ideal Mixture Behavior: Partial Miscibility
38:21
Spinodal Decomposition
42:11
The “Ouzo Effect”
54:06
Introduction to Systems with Chemical Reactions
54:27
Energy and Entropy Balances with Chemical Reaction
1:07:06
Notation and Stoichiometry: Reaction Coordinates
1:19:23
Proportionality Relations; Properties of Reaction
1:28:42
Enthalpy of Formation Illustrated on a H-S Diagram
1:34:52
Van der Waals Forces versus Covalent Bonds
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