Lecture 7: Availability Functions and the LeChatelier-Braun Principle
MIT 2.43 Advanced Thermodynamics, Spring 2024
Instructor: Gian Paolo Beretta
View the complete course: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/
Complete course table of contents with hyperlinks to slides and video timestamps: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_toc_slides_pdf/
Complete course analytical index with hyperlinks to slides and video timestamps: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_index_slides_pdf/
YouTube Playlist: https://www.youtube.com/playl…
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Chapters (20)
Introduction
0:16
Review: Legendre Transform
2:39
Review: Characteristic Functions
2:57
Review: Maxwell Relations
3:10
Jacobian Determinants
17:57
Cyclic Relation
25:22
Mayer Relation
30:01
Back to Availability Functions
30:09
Available Energy (Fixed Volume and Amounts)
38:59
Stability Conditions from Available Energy
39:57
Stability and LeChatelier-Braun Principle
41:26
Available Energy (Variable Volume, Fixed Amounts)
48:26
Stability Conditions that Follow
57:54
Available Energy (One Variable Amount)
1:11:05
Stability Conditions that Follow
1:11:53
Available Energy (Variable Volume and All Amounts)
1:15:26
Stability Conditions that Follow
1:16:31
Other Stability Conditions
1:19:38
Stability and LeChatelier-Braun Principle (Part I)
1:19:52
LeChatelier-Braun
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