Lecture 18: Properties of Reaction; Heating Values and Exergy of Fuels; Adiabatic Flame Temperature
Skills:
ML Maths Basics60%
MIT 2.43 Advanced Thermodynamics, Spring 2024
Instructor: Gian Paolo Beretta
View the complete course: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/
Complete course table of contents with hyperlinks to slides and video timestamps: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_toc_slides_pdf/
Complete course analytical index with hyperlinks to slides and video timestamps: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_index_slides_pdf/
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP6309d0oJDiVo1CvxUQXJ2il
This lecture covers: Stoichiometry. Proportionality relation. Reactions of formation. Hess relation. Fictitious ideal gas state at standard temperature and pressure. Heating values and exergy of hydrocarbons. Adiabatic flame temperature. Unattainability of a reversible flame.
Instructor suggests to set viewing speed at 1.5 for faster learning.
Slides for this lecture: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_lec18_pdf/
Key moments:
00:00:00 - Introduction
00:00:17 - Review: Systems with Chemical Reactions
00:00:30 - Closed and Open Systems with Chemical Reactions
00:01:28 - Review: Notation and Proportionality Relations
00:01:52 - Review: Properties of Reaction
00:03:20 - Enthalpy of Formation Illustrated on a H-S Diagram
00:05:08 - Van der Waals Forces versus Covalent Bonds
00:07:12 - Enthalpy of Formation and Bond Energies
00:11:17 - Properties of Formation and Hess Relation
00:24:10 - Direction of Spontanueos Reaction
00:27:51 - When Is a Reaction Product- or Reactant-Favored?
00:44:49 - Maximum Work Obtainable; Minimum Work Required
00:47:19 - Oxidation of Hydrocarbons
00:54:21 - Heating Value and Exergy of a Fuel
00:55:58 - Lower and Higher Heating Values
01:05:27 - Adiabatic Flame Temperature
01:25:38 - Summary on an Energy vs Entropy Diagram
01:34:15 - Is a Reversible Combu
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Chapters (18)
Introduction
0:17
Review: Systems with Chemical Reactions
0:30
Closed and Open Systems with Chemical Reactions
1:28
Review: Notation and Proportionality Relations
1:52
Review: Properties of Reaction
3:20
Enthalpy of Formation Illustrated on a H-S Diagram
5:08
Van der Waals Forces versus Covalent Bonds
7:12
Enthalpy of Formation and Bond Energies
11:17
Properties of Formation and Hess Relation
24:10
Direction of Spontanueos Reaction
27:51
When Is a Reaction Product- or Reactant-Favored?
44:49
Maximum Work Obtainable; Minimum Work Required
47:19
Oxidation of Hydrocarbons
54:21
Heating Value and Exergy of a Fuel
55:58
Lower and Higher Heating Values
1:05:27
Adiabatic Flame Temperature
1:25:38
Summary on an Energy vs Entropy Diagram
1:34:15
Is a Reversible Combu
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